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Professor Apollo (Roscoe Orman)- inventor of solar-powered devices and owner of Sun Island.

Theresa (Victoria Justice)- a homeless Latino girl who longs to be a doctor she and Wheeler help each other, and the Planeteers help her get the money she needs for medical school.

Angela (Anna Chlumsky)- Joe's girlfriend and a school teacher who teaches him to read.

Joe (Macaulay Culkin)- an illiterate farmer.

Juan (Antonio Banderas)- a Brazilian park ranger.

Nae (Daniel Dae Kim)- Korean metal scrapyard owner

Pontus (Aaron Tveit)- a marine biologist and an inhabitant of Oceanus.

Gone, into the Ocean Protector, a research ship with a crane, submersible, helicopter, shark cage, and sensor for detecting approaching whales and other sea creatures so that the ship can be slowed down to avoid striking them) rather than harpoon them

Maseo (Ken Watanabe)- Takashi's father, a Japanese whaler who is exposed to the plight of the whale by his son, and decides to protect whales (and research them humanely and honestly, after Captain Planet transforms Plunder's whaling vessel, the Whale B.

Takashi (Ryunosuke Kamiki)- a Japanese conservationist, who points out to his father that Plunder's and Blight's whaling operation is merely to sell the whales' meat it has nothing to do with "research".

Shaman (Benjamin Bratt)- friend of Ma-Ti's and South American native knows all about the Amazon rain forest *Josh (Robert Redford)- desert tour guide *Sam Corroboree (Aaron Pedersen)- friend of the Planeteers an Australian reporter.Chief Morla (Djimon Hounsou)- the leader of a Zimbabwean tribe, who realizes that damming the river will destroy his people's way of life.Chief Kofi (Peter Mensah)- current leader of Kwame's tribe.Mabutu (Fana Mokoena)- African game rancher and childhood friend of Kwame's Leela (Yara Shahidi)- Vico's sister, who longs to be a scientist and proves to their parents that women can do any job men can do.Vico (Karan Brar)- a boy from the island of Moghal, who is subjected to Plunder's and Blight's cloning experiment.Mohan (Prakash Raj)- Indian tiger tracker convinces the villagers to help preserve the tigers' habitat rather than bulldozing it for Greedly's golf course.

Commander Clash (Jason Momoa)- former soldier who assists the Planeteers.Nikki West (Amy Adams) - Wife of Tom West and housewife.Officer Tom West (Ben Stiller) - Police officer of Los Angeles Police Department, has two kids, and son of Randy West.Sun Horse (Zahn McClarnon)- chairman of the tribal council.Gray Eagle (Saginaw Grant)- shaman of Sky Runner's reservation.Sky Runner (Aaron White)- Native American rock star and owner of Eco Industries.Stalker Slaughter (Haley Joel Osment)- Eco-Villain Mame's son he and his mother commit wildlife crimes together.Mame Slaughter (Carol Hoyt)- Eco-Villain a wildlife poacher and smuggler.General Baz (Nathaniel Parker)- Zarm's right-hand man, who begins to obey Zarm's orders but ends up doing the right thing on the Earth's behalf.Zarm (Eric Idle)- the spirit of war and destruction.Rigger (Mike White)- Greedly's sidekick.Hoggish Greedly (Devin Ratray)- Eco-Villain.Verminous Skumm (Robert Stanton)- Eco-Villain.Leadsuit (Rick Moranis)- Nukem's sidekick.MAL (voiced by Rowan Atkinson)- Blight's computerized assistant his name stands for "Mean And Low".Argos Bleak (Hugh Jackman)- Plunder's bodyguard.Looten Plunder (Steve Valentine)- Eco-Villain.Captain Planet (Jamie Barber) - Summoned when the five powers combined.Ma-Ti (Rick Gonzalez) - From South America with the power of Heart.Gi (Jamie Chung) - From Asia with the power of Water.Linka (Scarlett Johansson) - From eastern Europe with the power of Wind.Wheeler (Seann William Scott) - From North America with the power of Fire.Kwame (Wesley Jonathan) - From Africa with the power of Earth.Gaia (Roselyn Sanchez)- the spirit of the Earth.Gaia calls in the five Planeteers in Los Angeles, California (Kwame, Wheeler, Linka, Gi, and Ma-Ti) to combine their powers to summon Captain Planet to protect Earth's enviroment.